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double type fzero error in vapor pressure calc

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%%%Hi, pretty new with MatLab but think I understand what I'm doing, for some reason keep getting an error about 'double' type arguments in the fzero function.
%%%I made this mfile to define function for which I need the root:
function y=deltaphi(Pguess)
Tc=507.6;%K
Pc=30.25;%bar
w=0.301;
T=341.9%K
R=8.3144598*10^(-5);%m3 bar / K mol
f=0.480+1.574*w-0.176*w^2;
ac=0.42748*(R^2)*(Tc^2)/Pc;
a=ac*(1+f*(1-(T/Tc)^(1/2)))^2;
b=0.08664*R*Tc/Pc;
syms V
SRK=Pguess==R*T/(V-b)-a/(V*(V-b));
V=solve(SRK,V,'Real',true)
V=V(V>0)
Vl=double(min(V))
Vv=double(max(V))
Zl=R*T/(Pguess*Vl)
Zv=R*T/(Pguess*Vv)
phi_l=exp(Zl-1-log(Zl)-log(1-b/Vl)-(a/(b*R*T))*log(1+b/Vl))
phi_v=exp(Zl-1-log(Zl)-log(1-b/Vv)-(a/(b*R*T))*log(1+b/Vv))
y=phi_l/phi_v-1
end
%%%%Then I wrote this script file to find a good starting point for the fzero function: R=8.3144598*10^(-5);
T=341.9;
a=3.*10^(-5);
b=1.2088*10^(-4);
syms V
SRK=R*T/(V-b)-a/(V*(V-b));
Vext=solve(diff(SRK,'V')==0,V,'Real',true);
Vext=Vext(Vext>b);
Vmax=max(Vext);
Vmin=min(Vext);
Pmin=max(10*(-7),R*T/(Vmin-b)-a/(Vmin*(Vmin-b)))
Pmax=max(R*T/(Vmax-b)-a/(Vmax*(Vmax-b)))
Pguess=Pmin:0.99*Pmax
Pvap=fzero(@deltaphi,double(Pguess))
%%%Any help would be much appreciated. This is the exact error message
"Error using fzero (line 412) Second argument must be a scalar or vector of length 2.
Error in pvap (line 14) Pvap=fzero(@deltaphi,double([Pmin:0.99*Pmax]))"

Answers (1)

Torsten
Torsten on 22 Feb 2016
And - is double(Pguess) a scalar or a vector of length 2 ? No, it isn't.
As the second argument in the call to fzero, you have to supply a starting guess or a starting interval for the solution, thus a scalar or a vector of length 2.
Best wishes
Torsten.

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