Error using bvp4c (line 251) Unable to solve the collocation equations -- a singular Jacobian encountered.

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Hello
I'm trying to solve an ODE, but getting the following error:
Error using bvp4c (line 251)
Unable to solve the collocation equations -- a singular Jacobian encountered.
Here is my code:
Diff=7.0000e-11;
koffPart=5.1910e-06;
konPart=6.7702e-18;
CT=1.2044e+17;
LT=1.2044e+16;
xmesh = linspace(0,1000,100);
solinit = bvpinit(xmesh, @guess);
sol = bvp4c(@(t,C) odefcn(t,C,Diff,konPart,koffPart,CT,LT), @(Ca,Cb) bcfcn(Ca,Cb,CT), solinit);
Here is my ODE function:
function dCdt = odefcn(t,C,Diff,konPart,koffPart,CT,LT)
dCdt=zeros(2,1);
dCdt(1)=C(2);
dCdt(2)=(C(2)+konPart*C(1)*(LT-CT+C(1))-koffPart*(CT-C(1)))/Diff;
end
Here are my boundary conditions:
function res = bcfcn(Ca,Cb,CT)
res = [Ca(1)-CT
Cb(2)];
end
And my guess:
function g = guess(x)
g = [exp(-x)
-exp(-x)];
end
I'd really appreiate any help.
Thanks!
Ben
  6 Comments
Muhammad Safdar Nadeem
Muhammad Safdar Nadeem on 30 Oct 2022
please help me in this error
Error using bvp4c (line 251)
Unable to solve the collocation equations -- a singular Jacobian encountered.
Error in newpapercodeH (line 28)
sol1 = bvp4c(@bvpexam2, @bcexam2, sol);
Torsten
Torsten on 30 Oct 2022
Edited: Torsten on 30 Oct 2022
You use
res=[y0(1)+2*S/m+1;y0(2)-0;y0(4)-1;yinf(2)-1;yinf(4)-0];
in your code, but m = 0. So S/m means that you divide by 0.
Maybe you meant S/(m+1) instead of S/m+1.

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Accepted Answer

Harshendra Shah
Harshendra Shah on 7 Apr 2020
Hi Ben,
A singular Jacobian indicates that the initial guess causes the solution to diverge. The BVP4C function finds the solution by solving a system of nonlinear algebraic equations. Nonlinear solvers are only as effective as the initial guess they start with, so changing your starting guess may help. Also, BVP4C is responsible for providing a guess for the solution from one iteration to another.
This MATLAB Answer also suggests some workarounds to solve this issue.
I hope this helps.

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